10:20 - 10:50
Room: Room3
keynote speaker
Chair/s:
Xiaobing Ren
(INVITED) On the paraelectric behavior of water at T = T* = 60 ºC as a polar liquid
Julio A. Gonzalo 2, Juan Carlos del Valle 1, Carmen Aragó 2, Manuel Marqués 2, Ginés Lifante 2, Daniel Jaque 2, José García Solé 2, Manuel Tello 3, Francisco Jaque 2
1 Departamento Química Física C 02 Universidad Autónoma de Madrid 28049 Madrid, Madrid, Spain
2 Departamento Física Materiales C 04 Universidad Autónoma de Madrid 28049 Madrid, Madrid, Spain
3 Facultad de ciencia y Tecnología Universidad del País Vasco 48080, Bilbao, Spain

Curie-Weiss like temperature dependence of the dielectric permitivity has been shown to take place in water. A bi-linear change at T*= 60 ºC has been reported recently. In this work an effective field statistical theory is developed for polar liquids such as water which describes well its behavior through T*. It implies a change in dipole moment from a value close to that in ice to a value close to that in water vapor. The Lindemann relationship is used to estimate the fractional oscillation of the water molecule from melting temperature to T* and beyond in terms of the Debye temperature of water TDebye = 224 K.


Reference:
Th-S60-O-01
Presenter/s:
Julio A. Gonzalo
Presentation type:
Oral communication
Room:
Room3
Chair/s:
Xiaobing Ren
Date:
Thursday, September 7th, 2017
Time:
10:20 - 10:50
Session times:
10:20 - 10:50